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Preparation of solution-processable colorless polyamide-imides with extremely low thermal expansion coefficients through an in-situ silylation method for potential space optical applications
Wang, Song1; Yang, Guangjie2; Wu, Shibin1; Ren, Ge1; Yang, Wei1; Liu, Xikui2
2016
发表期刊E-Polymers
卷号16期号:5页码:395-402
文章类型J
摘要Several tough and flexible fluorinated polyamide-imide films were prepared from trimellitic anhydride chloride and 2,2'-bis(trifluoromethyl)benzidine through a facile one-pot in-situ silylation method. By incorporating fluorinated side groups, the solubility of the prepared polyamide-imide was greatly enhanced. Meanwhile, due to their linear chain configuration and the existence of hydrogen bonding, the prepared polyamide-imide films revealed high tensile strength, high tensile modulus, high glass transition temperature (Tg) and most interestingly, very low coefficient of thermal expansion (CTE) of 11 ppm/°C. Copolymerization with pyromellitic dianhydride (PMDA) led to an extremely low CTE of 4 ppm/°C which should be among the lowest values available for soluble polyamide-imides. The optical homogeneity and stress homogeneity of the obtained polyamide-imide films were also tested. After non-contact with substance and thermal treatment at 300°C, they revealed a better optical homogeneity and stress homogeneity than that of the commercially available Kapton polyimide (PI) films, with a PV value of 0.915 λ and RMS value of 0.163 λ. Thus, these colorless and soluble polyamide-imide films simultaneously possessing promising optical imaging performance are good candidates as novel diffractive membrane optical system architectures. © 2016 Walter de Gruyter GmbH, Berlin/Boston.
关键词Amines Fiber Optic Sensors Film Preparation Glass Bonding Glass Transition Hydrogen Bonds Optical Systems Polyamideimides Polyimides Synthesis (Chemical) Tensile Strength Thermal Expansion
DOI10.1515/epoly-2016-0100
收录类别Ei
语种英语
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ioe.ac.cn/handle/181551/8561
专题质量处(质检中心)
作者单位1. Institute of Optics and Electronics, Chinese Academy of Sciences, Chengdu, China
2. College of Polymer Science and Engineering, Sichuan University, Chengdu, China
推荐引用方式
GB/T 7714
Wang, Song,Yang, Guangjie,Wu, Shibin,et al. Preparation of solution-processable colorless polyamide-imides with extremely low thermal expansion coefficients through an in-situ silylation method for potential space optical applications[J]. E-Polymers,2016,16(5):395-402.
APA Wang, Song,Yang, Guangjie,Wu, Shibin,Ren, Ge,Yang, Wei,&Liu, Xikui.(2016).Preparation of solution-processable colorless polyamide-imides with extremely low thermal expansion coefficients through an in-situ silylation method for potential space optical applications.E-Polymers,16(5),395-402.
MLA Wang, Song,et al."Preparation of solution-processable colorless polyamide-imides with extremely low thermal expansion coefficients through an in-situ silylation method for potential space optical applications".E-Polymers 16.5(2016):395-402.
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